Utilization of red mud as catalyst in conversion of waste oil and waste plastics to fuel

The aim of this study was to investigate the possibilities of using a by-product (red mud) from alumina production as a catalyst for recovery of waste. The conversion of waste mineral oil (WMO) and waste mineral oil/municipal waste plastic (WMO/MWP) blends over red mud (RM), a commercial hydrocracking catalyst (silica–alumina), and a commercial hydrotreating catalyst (Ni–Mo/alumina) to fuel has been studied. The effect of the catalyst and the temperature on the product distribution (gas, liquid, and wax) and the properties of liquid products were investigated. In the case of hydrotreatment of WMO, the liquids obtained over RM at both 400° and 425°C had larger amounts of low-boiling hydrocarbons than that of thermal or catalytic treatment with hydrotreating catalyst. Gas chromatography and nuclear magnetic resonance analysis of the liquid products showed that RM had hydrogenation and cracking activity in hydrotreatment of WMO. In coprocessing of WMO with municipal waste plastics, temperature had an important effect as well as the amount of MWP in the blend and the catalyst type. The hydrocracking at 400°C produced no liquid product. In hydrocracking at 425°C, the product distribution varied with catalyst type and MWP amount. The commercial hydrocracking catalyst had more cracking ability in the conversion of WMO/MWP to liquid and gas fuel than RM. In the case of hydrocracking over RM, the largest amount of liquid having satisfactory quality was obtained only from the blend containing 20% MWP.     

Pore structure and adsorption properties of activated carbon prepared from granular molded waste paper

We have previously manufactured activated carbon using waste paper board, which was prepared by adding 8% phenol resin adhesive to torn waste newspaper and hot-pressing. In this study, the pretreatment process of the raw material was simplified; the waste paper was extruded to form granules. The activated carbon was manufactured by the carbon dioxide activation method using the granules as the raw material. The properties of the activated carbon were evaluated based on the pore structure, the iodine adsorption number, and the adsorption of toluene vapor in a sealed chamber. The activated carbon, which was manufactured at an activation temperature of 1100°C and a treatment time of 60min, exhibited a specific surface area of 1241m²/g and an iodine adsorption number of 1120mg/g. These results were similar to those obtained for two commercially available activated carbons. The extent of toluene vapor adsorption by this activated carbon was similar to that observed for the two commercial activated carbons over a period of 130min.     

Health risk assessment of PCDD/F emissions from a hazardous and medical waste incinerator in Turkey

A multimedia risk assessment procedure was conducted to determine the fate and transport of polychlorinated dibenzo-p-dioxin and polychlorinated dibenzofuran (PCDD/F) emissions from the Izmit Hazardous and Medical Waste Incinerator (IZAYDAS) in Turkey and their potential health risks. Congener concentrations in ambient air and their deposition rates were determined by an air dispersion model (ISCST3). Their transfer to some plant groups and animal tissues was predicted by food chain modeling. Exposure scenarios were produced based on three receptor groups (urban, semiurban, and rural) and five subgroups determined according to ages. Daily intakes of PCDD/Fs via exposure pathways were determined based on three different emission scenarios for each group and subgroup. Estimated incremental PCDD/F doses caused by the incinerator emissions in central-tendency scenario were computed as between 2.31 x 10(-6) and 0.008 pg TEQ kg(-1) bodyweight (bw) day(-1) on average for all the receptors other than infants in all the settings, while the range was 3.01 x 10(-5)-0.081 pg TEQ kg(-1) bw day(-1) for infants. Sensitivity analysis showed that the consumption of vegetal products and their locally grown fractions are the most significant parameters in the exposure to PCDD/Fs in the area.     

Thermal cracking of oils from waste plastics

Thermal cracking of decomposed waste plastic oil produces a good yield of olefins. The solvent extraction of such waste plastic oil seems to be efficient for increasing gas yields and recycling monomers. To assess the potential of monomer recovery from municipal waste plastics, the oils were cracked using a laboratory-scale quartz-tube reactor. The waste plastic oils were provided by two commercial plants of the Sapporo Plastic Recycle Co. and the Dohoh Recycle Center Co. in Japan. A model waste plastic oil made in a laboratory was also examined. Yields of ethene, propene, and other products were measured at different temperatures. Two-step pyrolysis reduces coking compared with the direct thermal degradation of plastics. The raffinates from waste plastic oils extracted by sulfolane were also cracked. The primary products were almost the same as those from nontreated oils. The maximum total gas yield was 78wt%–85wt% at 750°C, an increase of about 20wt% compared with that of nonextracted oil. Solvent extraction removes stable aromatic hydrocarbons such as styrene, which is more coked than cracked.     

A Paradigm of International Environmental Law: The Case for Controlling the Transboundary Movements of Hazardous Wastes

The production of large quantities of wastes globally has created a commercial activity involving the transfrontier shipments of hazardous wastes, intended to be managed at economically attractive waste-handling facilities located elsewhere. In fact, huge quantities of hazardous wastes apparently travel the world in search of “acceptable” waste management facilities. For instance, within the industrialized countries alone, millions of tonnes of potentially hazardous waste cross national frontiers each year on their way for recycling or to treatment, storage, and disposal facilities (TSDFs) because there is no local disposal capacity for these wastes, or because legal disposal or reuse in a foreign country may be more environmentally sound, or managing the wastes in the foreign country may be less expensive than at home. The cross-boundary traffic in hazardous wastes has lately been under close public scrutiny, however, resulting in the accession of several international agreements and laws to regulate such activities. This paper discusses and analyzes the most significant control measures and major agreements in this new commercial activity involving hazardous wastes. In particular, the discussion recognizes the difficulties with trying to implement the relevant international agreements among countries of vastly different socioeconomic backgrounds. Nonetheless, it is also noted that global environmental agreements will generally be a necessary component of ensuring adequate environmental protection for the world community—and thus a need for the careful implementation of such agreements and regulations.     

Introduction of a waste incineration tax: Effects on the Swedish waste flows

A tax on waste-to-energy incineration of fossil carbon in municipal solid waste from households was introduced in Sweden on July 1, 2006. The tax has led to higher incineration gate fees. One of the main purposes with the tax is to increase the incentive for recycling of materials, including biological treatment. We investigate whether and to what extent this effect can be expected. A spreadsheet model is developed in order to estimate the net marginal cost of alternative waste treatment methods, i.e., the marginal cost of alternative treatment minus avoided cost of incineration. The value of the households’ time needed for source separation is discussed and included. The model includes the nine largest fractions, totalling 85% (weight), of the household waste currently being sent to waste incineration: food waste, newsprint, paper packaging, soft and hard plastic packaging, diapers, yard waste, other paper waste, and non-combustible waste. Our results indicate that the incineration tax will have the largest effect on biological treatment of kitchen and garden waste, which may increase by 9%. The consequences of an incineration tax depend on: (a) the level of the tax, (b) whether the tax is based on an assumed average Swedish fossil carbon content or on the measured carbon content in each incineration plant, (c) institutional factors such as the cooperation between waste incinerators, and (d) technological factors such as the availability of central sorting of waste or techniques for measurement of fossil carbon in exhaust gases, etc. Information turns out to be a key factor in transferring the governing force of the tax to the households as well improving the households’ attitudes towards material recycling.     

Present status of the recycling of waste electrical and electronic equipment in Korea

In Korea due to rapid economical growth followed by urbanisation, breakage of large traditional families into small nuclear families, continuous changes in equipment features and capabilities causes tremendous increase in sale of new electrical and electronic equipment (EEE) and decrease in sale of used EEE. Subsequently, the ever-increasing quantity of waste electrical and electronic equipment (WEEE) has become a serious social problem and threat to the environment. Therefore, the gradual increase in the generation of WEEE intensifies the interest for recycling to conserve the resources and protect the environment. In view of the above, a review has been made related to the present status of the recycling of waste electrical and electronic equipment in Korea. This paper describes the present status of generation and recycling of waste electrical and electronic equipment, namely TVs, refrigerators, washing machines, air conditioners, personal computers and mobile phones in Korea. The commercial processes and the status of developing new technologies for the recycling of metallic values from waste printed circuit boards (PCBs) is also described briefly. Since 1998, three recycling centers are in full operation to recycle WEEE such as refrigerators, washing machines and air conditioners, having the total capacity of 880,000 units/year. All waste TVs are recently recycled on commission basis by several private recycling plants. The recycling of waste personal computers and mobile phones is insignificant in comparison with the amount of estimated obsolete those. Korea has adopted and enforced the extended producer responsibility (EPR) system. Korea is making consistent efforts to improve the recycling rate to the standards indicated in the EU directives for WEEE. Especially environmentally friendly and energy-saving technologies are being developed to recycle metal values from PCBs of WEEE.     

Fish bioassay monitoring of waste effluents

Spills of toxic materials into bodies of water receiving industrial waste discharges can be prevented only if frequent or continuous assessments of effluent quality can be made. Currently available methods can automatically measure individual physical or chemical waste components but cannot assess toxicity caused by the interaction of components or the presence of an unsuspected material. Aquatic organisms, in contrast, respond to their total environment and in this way integrate the effects of all the various chemical and physical waste parameters.This study evaluates the possibility of using the continuously and automatically recorded responses of fish to monitor the toxicity of industrial waste effluents. A review of previously developed toxicity monitoring systems is followed by a field evaluation of a method that uses the computer-monitored ventilatory patterns of 12 bluegills (Lepomis macrochirus Rafinesque) to monitor the toxicity of an industrial waste effluent as it flows into a river. No known toxic spills occurred in the effluent during the operation of this system, but acetone added to the effluent waste caused responses from the fish at concentrations which peaked near the 96-hr LC₅₀ level. Some responses were also noted when no known toxicant was present; these were related to environmental disturbances and system design problems. Recommendations are made for the design of future biologic monitoring units.     

畜禽沼液中抗生素和激素的微波处理

通过间歇处理和连续处理实验，探讨微波技术对沼液中四环素类抗生素和激素喹乙醇去除的效果。结果表明，沼液在微波间歇处理中，最优反应时间为40min。此条件下沼液中喹乙醇、土霉素、四环素和金霉素的去除率分别达到26％、49％、48％和70％；微波可显著提高可生化性，BOD5／COD值达到0．37。微波一好氧处理系统中COD与氨氮的去除率分别达到91％和93％，明显优于单独好氧处理。沼液微波连续处理中，最优HRT为90min，此时喹乙醇、土霉素、四环素和金霉素的去除率分别达到24％、45％、50％和74％；BOD5／COD值达到0．34。微波．好氧处理系统中COD与氨氮的去除率均为90％，优于单独好氧处理效果。     

二氯荧光黄为指示剂的硝酸银滴定法测定废水中氯化物

采用以二氯荧光黄为指示剂的硝酸银滴定法测定废水中氯化物。优化实验条件后,以该法测定质控样,相对误差-1.30%～2.70%,相对标准偏差0.10%～0.14%,加标回收率约为98%。用该法测定废水中氯化物是合理可行的。